Introduction to X-Ray Emission Spectrometry

6.1.2 Thick samples


The attenuation of the sample depends on the sample matrix and on its areal density:

If the product has a very large value, then

In that case, the Sherman expression simplifies, since the attenuation does no longer depend on the sample areal density, but only on the sample matrix:

and

Or for the case of monochromatic excitation becomes